P3_20180713
P3
Reference: Bérard R, Makasheva K, Demyk K, Simon A, Nuñez Reyes D, Mastrorocco F, Sabbah H and Joblin C (2021) Impact of Metals on (Star)Dust Chemistry: A Laboratory Astrophysics Approach. Front. Astron. Space Sci. 8:654879. doi: 10.3389/fspas.2021.654879
m/z
calc m/z
delta m/z
Intensity (a.u)
Norm. I. (a.u)
DBE
DBE/C
H/C
Formula
Family
26.01
26.02
-0.003
3226.00
14.65
2.00
1.00
1.00
C2H2
HC Clusters
27.02
27.02
-0.001
142.00
0.64
2.00
1.00
1.00
C2H2
HC Clusters
27.98
27.98
0.001
470.00
2.13
0.00
0.00
0.00
Si
Elements
31.02
31.02
0.002
215.00
0.98
0.00
0.00
0.00
COH3
Oxygen Species (CxHyOk)
33.03
33.03
-0.003
172.00
0.78
0.00
0.00
0.00
COH5
Oxygen Species (CxHyOk)
38.01
38.02
-0.003
589.00
2.67
3.00
1.00
0.67
C3H2
HC Clusters
38.96
38.96
-0.001
1135.00
5.15
0.00
0.00
0.00
K
Elements
39.02
39.02
-0.001
3646.00
16.55
2.50
0.83
1.00
C3H3
HC Clusters
41.04
41.04
-0.002
368.00
1.67
1.50
0.50
1.67
C3H5
HC Clusters
42.01
42.01
0.002
158.29
0.72
0.00
0.00
0.00
COCH2
Oxygen Species (CxHyOk)
43.00
43.00
-0.002
263.00
1.19
0.00
0.00
0.00
SiCH3
Elements
43.02
43.02
-0.003
167.00
0.76
0.00
0.00
0.00
COCH3
Oxygen Species (CxHyOk)
44.98
44.98
0.002
5560.00
25.25
0.00
0.00
0.00
SiOH
Elements
45.98
45.98
-0.001
354.00
1.61
0.00
0.00
0.00
SiOH
Elements
46.97
46.98
-0.003
335.00
1.52
0.00
0.00
0.00
SiOH
Elements
50.02
50.02
0.002
1171.00
5.32
4.00
1.00
0.50
C4H2
HC Clusters
51.02
51.02
0.001
1334.00
6.06
3.50
0.88
0.75
C4H3
HC Clusters
52.03
52.03
0.003
154.00
0.70
3.00
0.75
1.00
C4H4
HC Clusters
53.01
53.00
0.007
107.07
0.49
0.00
0.00
0.00
C3OH
Oxygen Species (CxHyOk)
53.04
53.04
0.002
143.00
0.65
2.50
0.62
1.25
C4H5
HC Clusters
55.02
55.02
0.001
213.00
0.97
0.00
0.00
0.00
C3H3O
Oxygen Species (CxHyOk)
55.06
55.05
0.004
281.00
1.28
1.50
0.38
1.75
C4H7
HC Clusters
57.08
57.07
0.010
151.00
0.69
0.50
0.12
2.25
C4H9
HC Clusters
59.00
58.99
0.002
148.00
0.67
0.00
0.00
0.00
SiOCH3
Elements
61.01
61.01
0.003
195.00
0.89
0.00
0.00
0.00
SiOCH5
Elements
62.02
62.02
0.002
299.00
1.36
0.00
0.00
0.00
SiOCH6
Elements
63.03
63.02
0.006
578.00
2.62
4.50
0.90
0.60
C5H3
HC Clusters
64.03
64.03
0.001
90.00
0.41
4.00
0.80
0.80
C5H4
HC Clusters
65.05
65.04
0.011
1198.00
5.44
3.50
0.70
1.00
C5H5
HC Clusters
66.05
66.05
-0.000
249.00
1.13
3.00
0.60
1.20
C5H6
HC Clusters
67.06
67.05
0.004
150.00
0.68
2.50
0.50
1.40
C5H7
HC Clusters
69.08
69.07
0.013
784.00
3.56
1.50
0.30
1.80
C5H9
HC Clusters
70.07
70.08
-0.005
138.00
0.63
1.00
0.20
2.00
C5H10
HC Clusters
74.02
74.02
0.007
701.00
3.18
6.00
1.00
0.33
C6H2
HC Clusters
75.02
75.02
0.001
546.00
2.48
5.50
0.92
0.50
C6H3
HC Clusters
76.04
76.03
0.010
542.00
2.46
5.00
0.83
0.67
C6H4
Aromatics
77.05
77.04
0.011
715.00
3.25
4.50
0.75
0.83
C6H5
Aromatics
78.06
78.05
0.010
678.00
3.08
4.00
0.67
1.00
C6H6
Aromatics
81.04
81.04
0.000
163.00
0.74
0.00
0.00
0.00
SiCO2H9
Elements
81.08
81.07
0.007
428.00
1.94
2.50
0.42
1.50
C6H9
HC Clusters
85.00
85.01
-0.003
78.00
0.35
7.50
1.07
0.14
C7H
HC Clusters
86.02
86.02
0.005
295.00
1.34
7.00
1.00
0.29
C7H2
HC Clusters
87.03
87.02
0.004
222.00
1.01
6.50
0.93
0.43
C7H3
HC Clusters
88.04
88.03
0.008
344.00
1.56
6.00
0.86
0.57
C7H4
Aromatics
88.97
88.97
-0.004
212.00
0.96
0.00
0.00
0.00
Si3H5
Elements
89.05
89.04
0.010
606.00
2.75
5.50
0.79
0.71
C7H5
Aromatics
90.05
90.05
0.001
154.00
0.70
5.00
0.71
0.86
C7H6
Aromatics
91.06
91.05
0.006
881.00
4.00
4.50
0.64
1.00
C7H7
Aromatics
92.06
92.06
0.004
119.00
0.54
4.50
0.64
1.00
C7H7
Aromatics
93.03
93.02
0.011
73.00
0.33
0.00
0.00
0.00
SiC5H5
Elements
93.05
93.03
0.018
109.00
0.49
0.00
0.00
0.00
C6H5O
Oxygen Species (CxHyOk)
95.06
95.05
0.007
489.00
2.22
0.00
0.00
0.00
C6H7O
Oxygen Species (CxHyOk)
102.05
102.05
0.003
343.00
1.56
6.00
0.75
0.75
C8H6
Aromatics
106.91
106.90
0.009
9853.00
44.74
0.00
0.00
0.00
Ag
Elements
108.91
108.90
0.009
8581.00
38.96
0.00
0.00
0.00
Ag
Elements
113.04
113.04
-0.001
439.00
1.99
7.50
0.83
0.56
C9H5
Aromatics
113.04
113.04
-0.001
439.00
1.99
7.50
0.83
0.56
C9H5
Aromatics
115.06
115.05
0.003
4405.00
20.00
6.50
0.72
0.78
C9H7
Aromatics
116.06
116.06
-0.003
555.00
2.52
6.00
0.67
0.89
C9H8
Aromatics
123.03
123.02
0.008
90.00
0.41
9.50
0.95
0.30
C10H3
HC Clusters
123.95
123.91
0.042
276.00
1.25
0.00
0.00
0.00
AgOH
Elements
124.92
124.92
0.006
445.00
2.02
0.00
0.00
0.00
AgH2O
Elements
125.03
125.04
-0.010
119.95
0.54
8.50
0.85
0.50
C10H5
Aromatics
125.94
125.91
0.028
358.00
1.63
0.00
0.00
0.00
AgOH
Elements
126.04
126.05
-0.002
1378.00
6.26
8.00
0.80
0.60
C10H6
Aromatics
126.92
126.92
0.009
354.00
1.61
0.00
0.00
0.00
AgH2O
Elements
127.06
127.05
0.009
307.00
1.39
7.50
0.75
0.70
C10H7
Aromatics
128.06
128.06
-0.005
2717.00
12.34
7.00
0.70
0.80
C10H8
Aromatics
129.06
129.07
-0.006
898.00
4.08
6.50
0.65
0.90
C10H9
Aromatics
131.06
131.09
-0.025
153.00
0.69
5.50
0.55
1.10
C10H11
Aromatics
132.92
132.92
-0.001
167.00
0.76
0.00
0.00
0.00
AgC2H2
Elements
134.93
134.92
0.014
126.00
0.57
0.00
0.00
0.00
AgC2H2
Elements
135.03
135.02
0.004
160.00
0.73
10.50
0.95
0.27
C11H3
HC Clusters
138.04
138.05
-0.008
112.00
0.51
9.00
0.82
0.55
C11H6
Aromatics
139.06
139.05
0.009
1277.00
5.80
8.50
0.77
0.64
C11H7
Aromatics
140.06
140.06
-0.001
321.00
1.46
8.00
0.73
0.73
C11H8
Aromatics
141.07
141.07
0.002
1252.00
5.68
7.50
0.68
0.82
C11H9
Aromatics
142.08
142.08
-0.001
389.00
1.77
7.00
0.64
0.91
C11H10
Aromatics
143.09
143.09
-0.000
122.24
0.56
6.50
0.59
1.00
C11H11
Aromatics
144.94
144.92
0.023
138.99
0.63
0.00
0.00
0.00
AgC3H2
Elements
145.07
145.06
0.005
312.36
1.42
0.00
0.00
0.00
C10H9O
Oxygen Species (CxHyOk)
146.92
146.92
-0.001
152.00
0.69
0.00
0.00
0.00
AgC3H2
Elements
148.04
148.03
0.007
122.00
0.55
11.00
0.92
0.33
C12H4
HC Clusters
149.04
149.04
-0.001
627.00
2.85
10.50
0.88
0.42
C12H5
Aromatics
150.05
150.05
0.002
3601.00
16.35
10.00
0.83
0.50
C12H6
Aromatics
150.88
150.88
0.003
771.00
3.50
0.00
0.00
0.00
AgSiO
Elements
151.06
151.05
0.009
940.00
4.27
9.50
0.79
0.58
C12H7
Aromatics
152.07
152.06
0.008
6169.00
28.01
9.00
0.75
0.67
C12H8
Aromatics
152.88
152.88
0.008
895.00
4.06
0.00
0.00
0.00
AgSiO
Elements
153.07
153.07
-0.000
1449.00
6.58
8.50
0.71
0.75
C12H9
Aromatics
154.07
154.08
-0.005
321.00
1.46
8.00
0.67
0.83
C12H10
Aromatics
155.09
155.09
0.004
337.00
1.53
7.50
0.62
0.92
C12H11
Aromatics
156.10
156.09
0.006
163.00
0.74
7.00
0.58
1.00
C12H12
Aromatics
156.92
156.92
0.004
243.00
1.10
0.00
0.00
0.00
AgC4H2
Elements
158.91
158.92
-0.007
300.00
1.36
0.00
0.00
0.00
AgC4H2
Elements
161.04
161.04
0.000
217.00
0.99
11.50
0.88
0.38
C13H5
Aromatics
162.04
162.05
-0.002
297.00
1.35
11.00
0.85
0.46
C13H6
Aromatics
162.86
162.86
0.005
224.00
1.02
0.00
0.00
0.00
AgSi2
Elements
163.06
163.05
0.008
1083.00
4.92
10.50
0.81
0.54
C13H7
Aromatics
164.07
164.06
0.004
834.00
3.79
10.00
0.77
0.62
C13H8
Aromatics
164.88
164.86
0.020
163.00
0.74
0.00
0.00
0.00
AgSi2
Elements
165.08
165.07
0.009
3249.00
14.75
9.50
0.73
0.69
C13H9
Aromatics
166.07
166.08
-0.003
844.00
3.83
9.00
0.69
0.77
C13H10
Aromatics
167.08
167.09
-0.009
347.00
1.58
8.50
0.65
0.85
C13H11
Aromatics
168.09
168.09
-0.003
154.00
0.70
8.00
0.62
0.92
C13H12
Aromatics
169.07
169.06
0.004
1334.00
6.06
0.00
0.00
0.00
C12H9O
Oxygen Species (CxHyOk)
170.07
170.07
-0.003
282.00
1.28
0.00
0.00
0.00
C12H9O
Oxygen Species (CxHyOk)
170.90
170.90
-0.004
178.00
0.81
0.00
0.00
0.00
AgC4O
Elements
171.02
171.02
-0.001
124.00
0.56
13.50
0.96
0.21
C14H3
HC Clusters
173.04
173.04
0.001
113.00
0.51
12.50
0.89
0.36
C14H5
Aromatics
174.05
174.05
-0.001
1576.00
7.16
12.00
0.86
0.43
C14H6
Aromatics
175.06
175.05
0.002
528.00
2.40
11.50
0.82
0.50
C14H7
Aromatics
176.07
176.06
0.008
3245.00
14.73
11.00
0.79
0.57
C14H8
Aromatics
177.06
177.07
-0.006
1484.00
6.74
10.50
0.75
0.64
C14H9
Aromatics
178.08
178.08
0.005
4756.00
21.59
10.00
0.71
0.71
C14H10
Aromatics
179.09
179.09
0.008
1244.00
5.65
9.50
0.68
0.79
C14H11
Aromatics
180.08
180.09
-0.009
633.00
2.87
9.00
0.64
0.86
C14H12
Aromatics
181.09
181.10
-0.013
175.00
0.79
8.50
0.61
0.93
C14H13
Aromatics
182.08
182.11
-0.032
136.00
0.62
8.00
0.57
1.00
C14H14
Aromatics
185.06
185.04
0.024
298.56
1.36
13.50
0.90
0.33
C15H5
Aromatics
186.04
186.05
-0.002
255.00
1.16
13.00
0.87
0.40
C15H6
Aromatics
187.06
187.05
0.006
628.00
2.85
12.50
0.83
0.47
C15H7
Aromatics
188.07
188.06
0.003
439.00
1.99
12.00
0.80
0.53
C15H8
Aromatics
189.07
189.07
-0.002
2653.00
12.05
11.50
0.77
0.60
C15H9
Aromatics
190.08
190.08
0.002
1073.00
4.87
11.00
0.73
0.67
C15H10
Aromatics
191.08
191.09
-0.005
2063.00
9.37
10.50
0.70
0.73
C15H11
Aromatics
192.09
192.09
-0.003
1127.00
5.12
10.00
0.67
0.80
C15H12
Aromatics
193.07
193.06
0.002
1315.00
5.97
0.00
0.00
0.00
C14H9O
Oxygen Species (CxHyOk)
194.08
194.07
0.013
130.00
0.59
0.00
0.00
0.00
C14H9O
Oxygen Species (CxHyOk)
196.96
196.95
0.008
136.00
0.62
0.00
0.00
0.00
AgC7H6
Elements
198.05
198.05
0.000
1152.00
5.23
14.00
0.88
0.38
C16H6
Aromatics
198.95
198.95
0.002
131.00
0.59
0.00
0.00
0.00
AgC7H6
Elements
199.05
199.05
-0.004
1028.00
4.67
13.50
0.84
0.44
C16H7
Aromatics
200.07
200.06
0.007
9312.00
42.28
13.00
0.81
0.50
C16H8
Aromatics
201.07
201.07
-0.005
6519.00
29.60
12.50
0.78
0.56
C16H9
Aromatics
202.09
202.08
0.011
17696.00
80.35
12.00
0.75
0.62
C16H10
Aromatics
203.08
203.09
-0.008
3672.00
16.67
11.50
0.72
0.69
C16H11
Aromatics
204.09
204.09
0.005
248.30
1.13
11.50
0.72
0.69
C16H11
Aromatics
213.06
213.07
-0.014
144.00
0.65
13.50
0.79
0.53
C17H9
Aromatics
213.81
213.81
0.004
22024.00
100.00
0.00
0.00
0.00
Ag2
Elements
215.82
215.81
0.013
20290.11
92.13
0.00
0.00
0.00
Ag2
Elements
217.80
217.81
-0.007
17230.00
78.23
0.00
0.00
0.00
Ag2
Elements
219.06
219.08
-0.018
2126.00
9.65
0.00
0.00
0.00
C16H11O
Oxygen Species (CxHyOk)
238.78
238.82
-0.042
106.00
0.48
0.00
0.00
0.00
Ag2C2H
Elements
240.75
240.82
-0.066
126.00
0.57
0.00
0.00
0.00
Ag2C2H
Elements
241.73
241.82
-0.091
127.00
0.58
0.00
0.00
0.00
Ag2C2H2
Elements
242.87
242.82
0.054
119.00
0.54
0.00
0.00
0.00
Ag2C2H
Elements
243.72
243.82
-0.108
132.00
0.60
0.00
0.00
0.00
Ag2C2H2
Elements
251.01
251.09
-0.078
126.00
0.57
15.50
0.78
0.55
C20H11
Aromatics
320.71
320.71
-0.002
604.00
2.74
0.00
0.00
0.00
Ag3
Elements
322.70
322.71
-0.010
1955.00
8.88
0.00
0.00
0.00
Ag3
Elements
324.70
324.71
-0.012
1494.00
6.78
0.00
0.00
0.00
Ag3
Elements
326.72
326.71
0.007
658.00
2.99
0.00
0.00
0.00
Ag3
Elements
344.73
344.71
0.014
114.00
0.52
0.00
0.00
0.00
Ag3C2
Elements
346.72
346.71
0.002
410.00
1.86
0.00
0.00
0.00
Ag3C2
Elements
348.70
348.71
-0.010
315.00
1.43
0.00
0.00
0.00
Ag3C2
Elements
350.68
350.71
-0.030
117.00
0.53
0.00
0.00
0.00
Ag3C2
Elements
534.56
534.52
0.032
127.00
0.58
0.00
0.00
0.00
Ag5
Elements
536.53
536.53
0.006
262.00
1.19
0.00
0.00
0.00
Ag5
Elements
538.55
538.52
0.025
357.00
1.62
0.00
0.00
0.00
Ag5
Elements
540.53
540.52
0.007
321.00
1.46
0.00
0.00
0.00
Ag5
Elements
542.53
542.52
0.010
145.00
0.66
0.00
0.00
0.00
Ag5
Elements
566.54
566.50
0.041
190.00
0.86
0.00
0.00
0.00
Ag5Si
Elements
568.53
568.50
0.032
157.00
0.71
0.00
0.00
0.00
Ag5Si
Elements
Spectre
High
Low
Family composition by number of peaks (Tot: 164)
Family composition by absolute intensity peaks
Carbon families by number of peaks (Tot: 96)
Carbon families by absolute intensity peaks
DBE vs Carbon number
DBE/C vs Carbon number
H vs Carbon number
Identity
Name: P3
Date: 2018-07-13
Version: 1-
Operator: Hassan Sabbah, Rémi Bérard
Contact: hassan.sabbah@irap.omp.eu
Institution: IRAP
Description
Category: Plasma dust
Phase: Silver Nanoparticles in organosilicon dust
Precursors: HMDSO and Ag
Instrument: AROMA
Preparation: Silver sputtering during organosilicon dust growth in a Ar/HMDSO cold plasma (3 generations)
Comments:
Laser Fluence
Laser desorption E d (mJ/cm2 ): 150
Laser ionisation E j (mJ/cm2 ): 16
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