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P2

Reference: Bérard R, Makasheva K, Demyk K, Simon A, Nuñez Reyes D, Mastrorocco F, Sabbah H and Joblin C (2021) Impact of Metals on (Star)Dust Chemistry: A Laboratory Astrophysics Approach. Front. Astron. Space Sci. 8:654879. doi: 10.3389/fspas.2021.654879
m/z calc m/z delta m/z Intensity (a.u) Norm. I. (a.u) DBE DBE/C H/C Formula Family
26.01 26.02 -0.003 6734.00 23.22 2.00 1.00 1.00 C2H2 HC Clusters
27.97 27.98 -0.004 3438.00 11.86 0.00 0.00 0.00 Si Elements
30.03 30.05 -0.013 385.00 1.33 0.00 0.00 3.00 C2H6 HC Clusters
31.01 31.02 -0.003 328.00 1.13 0.00 0.00 0.00 CH3O Oxygen Species (CxHyOk)
33.04 33.03 0.002 155.00 0.53 0.00 0.00 0.00 CH5O Oxygen Species (CxHyOk)
38.01 38.02 -0.003 631.00 2.18 3.00 1.00 0.67 C3H2 HC Clusters
38.96 38.96 -0.001 2218.00 7.65 0.00 0.00 0.00 K Elements
39.02 39.02 -0.001 6214.00 21.43 2.50 0.83 1.00 C3H3 HC Clusters
41.04 41.04 -0.002 682.00 2.35 1.50 0.50 1.67 C3H5 HC Clusters
43.00 43.00 -0.002 706.00 2.43 0.00 0.00 0.00 SiCH3 Elements
44.05 44.06 -0.008 178.00 0.61 0.00 0.00 2.67 C3H8 HC Clusters
50.02 50.02 0.002 2147.00 7.40 4.00 1.00 0.50 C4H2 HC Clusters
51.02 51.02 0.001 6575.00 22.67 3.50 0.88 0.75 C4H3 HC Clusters
52.03 52.03 0.003 480.00 1.66 3.00 0.75 1.00 C4H4 HC Clusters
53.00 53.00 0.000 233.00 0.80 0.00 0.00 0.00 C3HO Oxygen Species (CxHyOk)
53.04 53.04 0.002 735.65 2.54 2.50 0.62 1.25 C4H5 HC Clusters
54.01 54.01 -0.004 170.00 0.59 0.00 0.00 0.00 C3H2O Oxygen Species (CxHyOk)
55.02 55.02 0.001 488.00 1.68 0.00 0.00 0.00 C3H3O Oxygen Species (CxHyOk)
55.05 55.05 -0.002 346.33 1.19 1.50 0.38 1.75 C4H7 HC Clusters
56.05 56.06 -0.007 155.00 0.53 1.00 0.25 2.00 C4H8 HC Clusters
57.07 57.07 0.004 152.00 0.52 0.50 0.12 2.25 C4H9 HC Clusters
58.07 58.08 -0.010 177.00 0.61 0.00 0.00 2.50 C4H10 HC Clusters
59.00 58.99 0.002 200.00 0.69 0.00 0.00 0.00 SiOCH3 Elements
61.01 61.01 0.003 1802.64 6.22 0.00 0.00 0.00 SiOCH5 Elements
62.01 62.02 -0.004 378.00 1.30 0.00 0.00 0.00 SiOCH6 Elements
63.03 63.02 0.006 1033.00 3.56 4.50 0.90 0.60 C5H3 HC Clusters
64.03 64.03 0.001 227.00 0.78 4.00 0.80 0.80 C5H4 HC Clusters
65.04 65.04 0.004 1654.00 5.70 3.50 0.70 1.00 C5H5 HC Clusters
66.05 66.05 0.007 212.59 0.73 3.00 0.60 1.20 C5H6 HC Clusters
67.06 67.05 0.004 418.00 1.44 2.50 0.50 1.40 C5H7 HC Clusters
69.07 69.07 -0.002 478.00 1.65 1.50 0.30 1.80 C5H9 HC Clusters
74.01 74.02 -0.001 530.00 1.83 6.00 1.00 0.33 C6H2 HC Clusters
75.02 75.02 0.001 1319.00 4.55 5.50 0.92 0.50 C6H3 HC Clusters
76.03 76.03 -0.005 428.00 1.48 5.00 0.83 0.67 C6H4 Aromatics
77.01 77.00 0.008 737.00 2.54 0.00 0.00 0.00 C5HO Oxygen Species (CxHyOk)
77.04 77.04 0.003 1077.00 3.71 4.50 0.75 0.83 C6H5 Aromatics
77.99 78.01 -0.016 189.00 0.65 0.00 0.00 0.00 C5H2O Oxygen Species (CxHyOk)
78.04 78.05 -0.006 375.00 1.29 4.00 0.67 1.00 C6H6 Aromatics
79.02 79.02 0.005 540.22 1.86 0.00 0.00 0.00 C5H3O Oxygen Species (CxHyOk)
79.05 79.05 -0.000 543.00 1.87 3.50 0.58 1.17 C6H7 Aromatics
80.06 80.06 -0.004 186.00 0.64 3.00 0.50 1.33 C6H8 Aromatics
85.01 85.01 0.005 155.00 0.53 7.50 1.07 0.14 C7H HC Clusters
86.01 86.02 -0.003 203.00 0.70 7.00 1.00 0.29 C7H2 HC Clusters
87.03 87.02 0.004 578.00 1.99 6.50 0.93 0.43 C7H3 HC Clusters
88.02 88.03 -0.008 229.00 0.79 6.00 0.86 0.57 C7H4 Aromatics
88.95 88.97 -0.020 443.00 1.53 0.00 0.00 0.00 Si3H5 Elements
89.03 89.04 -0.006 787.00 2.71 5.50 0.79 0.71 C7H5 Aromatics
91.06 91.05 0.006 2298.00 7.92 4.50 0.64 1.00 C7H7 Aromatics
93.02 93.02 0.003 237.02 0.82 0.00 0.00 0.00 SiC5H5 Elements
93.04 93.03 0.010 393.07 1.36 0.00 0.00 0.00 C6H5O Oxygen Species (CxHyOk)
95.01 95.05 -0.036 140.00 0.48 0.00 0.00 0.00 C6H7O Oxygen Species (CxHyOk)
97.00 97.01 -0.003 126.00 0.43 8.50 1.06 0.12 C8H HC Clusters
102.03 102.05 -0.016 108.00 0.37 6.00 0.75 0.75 C8H6 Aromatics
106.90 106.90 -0.005 14382.00 49.59 0.00 0.00 0.00 Ag Elements
115.05 115.05 -0.003 1172.89 4.04 6.50 0.72 0.78 C9H7 Aromatics
116.05 116.06 -0.007 267.00 0.92 6.00 0.67 0.89 C9H8 Aromatics
123.93 123.91 0.023 342.81 1.18 0.00 0.00 0.00 AgOH Elements
124.91 124.92 -0.004 773.00 2.67 0.00 0.00 0.00 AgH2O Elements
126.05 126.05 0.000 342.00 1.18 8.00 0.80 0.60 C10H6 Aromatics
127.05 127.05 -0.008 201.00 0.69 7.50 0.75 0.70 C10H7 Aromatics
128.07 128.06 0.005 726.00 2.50 7.00 0.70 0.80 C10H8 Aromatics
129.07 129.07 -0.003 426.00 1.47 6.50 0.65 0.90 C10H9 Aromatics
130.02 130.04 -0.016 100.00 0.34 0.00 0.00 0.00 C9H6O Oxygen Species (CxHyOk)
130.07 130.08 -0.009 79.00 0.27 6.00 0.60 1.00 C10H10 Aromatics
131.05 131.09 -0.032 155.00 0.53 5.50 0.55 1.10 C10H11 Aromatics
135.03 135.02 0.009 247.00 0.85 10.50 0.95 0.27 C11H3 HC Clusters
138.99 139.00 -0.014 185.00 0.64 0.00 0.00 0.00 SiC9H3 Elements
139.05 139.05 -0.002 846.00 2.92 8.50 0.77 0.64 C11H7 Aromatics
140.07 140.06 0.009 147.00 0.51 8.00 0.73 0.73 C11H8 Aromatics
141.01 141.02 -0.006 218.00 0.75 0.00 0.00 0.00 SiC9H5 Elements
141.06 141.07 -0.012 399.00 1.38 7.50 0.68 0.82 C11H9 Aromatics
142.07 142.08 -0.011 118.51 0.41 7.00 0.64 0.91 C11H10 Aromatics
143.03 143.03 -0.002 469.67 1.62 0.00 0.00 0.00 SiC9H7 Elements
143.09 143.09 -0.000 141.00 0.49 6.50 0.59 1.00 C11H11 Aromatics
144.92 144.92 0.001 260.00 0.90 0.00 0.00 0.00 AgC3H2 Elements
145.07 145.06 0.003 462.00 1.59 0.00 0.00 0.00 C10H9O Oxygen Species (CxHyOk)
148.03 148.03 -0.002 155.00 0.53 11.00 0.92 0.33 C12H4 HC Clusters
149.04 149.04 -0.002 374.00 1.29 10.50 0.88 0.42 C12H5 Aromatics
150.05 150.05 0.002 1029.00 3.55 10.00 0.83 0.50 C12H6 Aromatics
150.88 150.88 0.003 1064.00 3.67 0.00 0.00 0.00 AgSiO Elements
151.04 151.05 -0.013 344.00 1.19 9.50 0.79 0.58 C12H7 Aromatics
152.06 152.06 -0.003 3838.00 13.23 9.00 0.75 0.67 C12H8 Aromatics
153.07 153.07 -0.000 881.00 3.04 8.50 0.71 0.75 C12H9 Aromatics
154.08 154.08 0.003 252.00 0.87 8.00 0.67 0.83 C12H10 Aromatics
155.08 155.09 -0.005 207.03 0.71 7.50 0.62 0.92 C12H11 Aromatics
156.91 156.92 -0.007 353.00 1.22 0.00 0.00 0.00 AgC4H2 Elements
161.03 161.04 -0.011 221.00 0.76 11.50 0.88 0.38 C13H5 Aromatics
162.04 162.05 -0.002 184.73 0.64 11.00 0.85 0.46 C13H6 Aromatics
162.86 162.86 -0.001 230.00 0.79 0.00 0.00 0.00 AgSi2 Elements
163.05 163.05 -0.000 1292.00 4.46 10.50 0.81 0.54 C13H7 Aromatics
164.07 164.06 0.004 590.00 2.03 10.00 0.77 0.62 C13H8 Aromatics
165.07 165.07 0.001 2733.00 9.42 9.50 0.73 0.69 C13H9 Aromatics
166.07 166.08 -0.011 696.98 2.40 9.00 0.69 0.77 C13H10 Aromatics
167.07 167.09 -0.020 279.00 0.96 8.50 0.65 0.85 C13H11 Aromatics
169.06 169.06 -0.004 1564.00 5.39 0.00 0.00 0.00 C12H9O Oxygen Species (CxHyOk)
170.91 170.90 0.008 141.00 0.49 0.00 0.00 0.00 AgC4O Elements
171.02 171.02 -0.005 430.00 1.48 13.50 0.96 0.21 C14H3 HC Clusters
172.01 172.03 -0.018 190.00 0.66 13.00 0.93 0.29 C14H4 HC Clusters
172.99 172.95 0.039 144.00 0.50 0.00 0.00 0.00 AgC5H6 Elements
174.05 174.05 0.003 475.00 1.64 12.00 0.86 0.43 C14H6 Aromatics
175.05 175.05 -0.005 292.00 1.01 11.50 0.82 0.50 C14H7 Aromatics
176.06 176.06 0.001 2138.00 7.37 11.00 0.79 0.57 C14H8 Aromatics
177.07 177.07 -0.002 1195.00 4.12 10.50 0.75 0.64 C14H9 Aromatics
178.08 178.08 -0.000 3175.00 10.95 10.00 0.71 0.71 C14H10 Aromatics
179.07 179.09 -0.011 788.00 2.72 9.50 0.68 0.79 C14H11 Aromatics
180.09 180.09 -0.005 221.00 0.76 9.00 0.64 0.86 C14H12 Aromatics
181.06 181.06 -0.007 403.00 1.39 0.00 0.00 0.00 C13H9O Oxygen Species (CxHyOk)
182.94 182.94 0.009 123.00 0.42 0.00 0.00 0.00 AgC6H4 Elements
185.06 185.04 0.018 131.00 0.45 13.50 0.90 0.33 C15H5 Aromatics
186.04 186.05 -0.008 212.00 0.73 13.00 0.87 0.40 C15H6 Aromatics
187.05 187.05 -0.006 1175.00 4.05 12.50 0.83 0.47 C15H7 Aromatics
188.06 188.06 -0.002 749.00 2.58 12.00 0.80 0.53 C15H8 Aromatics
189.07 189.07 0.004 4538.00 15.65 11.50 0.77 0.60 C15H9 Aromatics
190.08 190.08 0.001 1806.00 6.23 11.00 0.73 0.67 C15H10 Aromatics
191.09 191.09 0.001 3045.00 10.50 10.50 0.70 0.73 C15H11 Aromatics
192.08 192.09 -0.009 884.00 3.05 10.00 0.67 0.80 C15H12 Aromatics
193.08 193.06 0.020 394.00 1.36 0.00 0.00 0.00 C14H9O Oxygen Species (CxHyOk)
196.96 196.95 0.012 186.00 0.64 0.00 0.00 0.00 AgC7H6 Elements
198.04 198.05 -0.007 364.00 1.26 14.00 0.88 0.38 C16H6 Aromatics
199.04 199.05 -0.011 374.00 1.29 13.50 0.84 0.44 C16H7 Aromatics
200.06 200.06 -0.001 7208.00 24.86 13.00 0.81 0.50 C16H8 Aromatics
201.06 201.07 -0.013 4383.00 15.11 12.50 0.78 0.56 C16H9 Aromatics
202.09 202.08 0.016 13020.00 44.90 12.00 0.75 0.62 C16H10 Aromatics
203.07 203.09 -0.016 3865.00 13.33 11.50 0.72 0.69 C16H11 Aromatics
212.05 212.06 -0.015 197.00 0.68 14.00 0.82 0.47 C17H8 Aromatics
213.05 213.07 -0.024 578.00 1.99 13.50 0.79 0.53 C17H9 Aromatics
213.82 213.81 0.007 28999.00 100.00 0.00 0.00 0.00 Ag2 Elements
219.07 219.08 -0.015 1705.00 5.88 0.00 0.00 0.00 C16H11O Oxygen Species (CxHyOk)
226.06 226.08 -0.018 470.00 1.62 14.00 0.78 0.56 C18H10 Aromatics
228.97 228.98 -0.010 368.96 1.27 0.00 0.00 0.00 AgC8H10O Elements
237.05 237.07 -0.017 228.00 0.79 15.50 0.82 0.47 C19H9 Aromatics
238.81 238.82 -0.004 150.37 0.52 0.00 0.00 0.00 Ag2C2H Elements
239.05 239.09 -0.039 368.60 1.27 14.50 0.76 0.58 C19H11 Aromatics
239.84 239.83 0.013 135.00 0.47 0.00 0.00 0.00 Ag2C2H2 Elements
250.05 250.08 -0.030 147.48 0.51 16.00 0.80 0.50 C20H10 Aromatics
320.72 320.71 0.003 5365.00 18.50 0.00 0.00 0.00 Ag3 Elements
344.71 344.71 -0.000 633.00 2.18 0.00 0.00 0.00 Ag3C2 Elements
376.70 376.67 0.029 128.95 0.44 0.00 0.00 0.00 Ag3Si2 Elements
402.99 402.97 0.021 511.00 1.76 0.00 0.00 0.00 AgC24H8 Elements
403.96 403.97 -0.011 358.00 1.23 0.00 0.00 0.00 AgC24H8 Elements
455.61 455.60 0.017 368.00 1.27 0.00 0.00 0.00 Ag4Si Elements
534.51 534.52 -0.014 323.00 1.11 0.00 0.00 0.00 Ag5 Elements
562.54 562.50 0.040 228.00 0.79 0.00 0.00 0.00 Ag5Si Elements

Spectre

Family composition by number of peaks (Tot: 143)

Family composition by absolute intensity peaks

Carbon families by number of peaks (Tot: 93)

Carbon families by absolute intensity peaks

DBE vs Carbon number

DBE/C vs Carbon number

H vs Carbon number

Identity

Name:P2
Date:2018-04-18
Version:1
Operator:Hassan Sabbah, Rémi Bérard
Contact:hassan.sabbah@irap.omp.eu
Institution:IRAP

Description

Category:Plasma dust
Phase:Silver Nanoparticles in organosilicon dust
Precursors:HMDSO and Ag
Instrument:AROMA
Preparation: Silver sputtering during organosilicon dust growth in a Ar/HMDSO cold plasma (5 generations)
Comments:

Laser Fluence

Laser desorption E d (mJ/cm2):150
Laser ionisation E j (mJ/cm2):16

Collaborators

Names:
Institutions:
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